通过模板合成形成的含P-N-N-P四齿配体的铁配合物催化的酮的高效不对称转移氢化反应。
Efficient asymmetric transfer hydrogenation of ketones catalyzed by an iron complex containing a P-N-N-P tetradentate ligand formed by template synthesis.
作者信息
Mikhailine Alexandre, Lough Alan J, Morris Robert H
机构信息
Davenport Laboratory, Department of Chemistry, University of Toronto, Toronto, Ontario M5S 3H6, Canada.
出版信息
J Am Chem Soc. 2009 Feb 4;131(4):1394-5. doi: 10.1021/ja809493h.
PMID:19133772
Abstract
A distorted iron complex formed by template synthesis is the basis of a very efficient and economical catalyst system for the asymmetric transfer hydrogenation of ketones for the production of valuable enantioenriched alcohols.
摘要
通过模板合成形成的扭曲铁络合物是一种非常高效且经济的催化剂体系的基础，该体系用于酮的不对称转移氢化反应以生产有价值的对映体富集醇。
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