Lan Anjian, Li Kunhao, Wu Haohan, Olson David H, Emge Thomas J, Ki Woosoek, Hong Maochun, Li Jing
Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, PR China.
Angew Chem Int Ed Engl. 2009;48(13):2334-8. doi: 10.1002/anie.200804853.
Sensors and sensitivity: A highly luminescent microporous metal-organic framework, [Zn(2)(bpdc)(2)(bpee)] (bpdc = 4,4'-biphenyldicarboxylate; bpee = 1,2-bipyridylethene), is capable of very fast and reversible detection of the vapors of the nitroaromatic explosive 2,4-dinitrotoluene and the plastic explosive taggant 2,3-dimethyl-2,3-dinitrobutane, through redox fluorescence quenching with unprecedented sensitivity (see spectra).
一种高发光性的微孔金属有机框架材料[Zn(2)(bpdc)(2)(bpee)](bpdc = 4,4'-联苯二甲酸;bpee = 1,2-联吡啶乙烯),能够通过氧化还原荧光猝灭,以前所未有的灵敏度非常快速且可逆地检测硝基芳香族炸药2,4-二硝基甲苯和塑料炸药示踪剂2,3-二甲基-2,3-二硝基丁烷的蒸汽(见光谱)。