Takigami Hidetaka, Suzuki Go, Hirai Yasuhiro, Ishikawa Yukari, Sunami Masakiyo, Sakai Shin-ichi
Research Center for Material Cycles and Waste Management, National Institute for Environmental Studies, Tsukuba 305-8506, Japan.
Environ Int. 2009 May;35(4):688-93. doi: 10.1016/j.envint.2008.12.007. Epub 2009 Jan 30.
Occurrence of flame retardants (FRs) in the indoor environment of highly flame-retarded public facilities is an important concern from the viewpoint of exposure because it is likely that FRs are used to a greater degree in these facilities than in homes. For this study, brominated flame-retardants (BFRs) and organophosphate flame-retardants and plasticizers (OPs), and brominated dibenzo-p-dioxins/furans (PBDD/DFs) were measured in eight floor dust samples taken from a Japanese commercial hotel that was assumed to have many flame-retardant materials. Concentrations of polybrominated diphenylethers (PBDEs) and hexabromocyclododecanes (HBCDs) varied by about two orders of magnitude, from 9.8-1700 ng/g (median of 1200 ng/g) and from 72-1300 ng/g (median of 740 ng/g), respectively. Concentrations of the two types of BFRs described above were most dominant among the investigated BFRs in the dust samples. It is inferred that BFR and PBDD/DF concentrations are on the same level as those in house and office dust samples reported based on past studies. Regarding concentrations of 11 OPs, 7 OPs were detected on the order of micrograms per gram, which are equivalent to or exceed the BFR concentrations such as PBDEs and HBCDs. Concentrations of the investigated compounds were not uniform among dust samples collected throughout the hotel: concentrations differed among floors, suggesting that localization of source products is associated with FR concentrations in dust. Passive air sampling was also conducted to monitor BFRs in the indoor air of hotel rooms: the performance of an air cleaner placed in the room was evaluated in terms of reducing airborne BFR concentrations. Monitoring results suggest that operation of an appropriate air cleaner can reduce both gaseous and particulate BFRs in indoor air.
从暴露的角度来看,高阻燃公共设施室内环境中阻燃剂(FRs)的存在是一个重要问题,因为这些设施中FRs的使用程度可能比家庭中更高。在本研究中,对从一家日本商业酒店采集的八个地板灰尘样本中的溴化阻燃剂(BFRs)、有机磷酸酯阻燃剂和增塑剂(OPs)以及溴化二苯并 - p - 二恶英/呋喃(PBDD/DFs)进行了测量,该酒店被认为使用了许多阻燃材料。多溴二苯醚(PBDEs)和六溴环十二烷(HBCDs)的浓度变化约两个数量级,分别为9.8 - 1700 ng/g(中位数为1200 ng/g)和72 - 1300 ng/g(中位数为740 ng/g)。上述两种BFRs的浓度在灰尘样本中所研究的BFRs中占主导地位。据推断,BFR和PBDD/DF的浓度与过去研究报道的家庭和办公室灰尘样本中的浓度处于同一水平。关于11种OPs的浓度,检测到7种OPs的浓度为每克微克级别,相当于或超过了PBDEs和HBCDs等BFRs的浓度。在整个酒店收集的灰尘样本中,所研究化合物的浓度并不均匀:各楼层之间存在差异,这表明源产品的局部化与灰尘中FR的浓度有关。还进行了被动空气采样以监测酒店房间室内空气中的BFRs:根据减少空气中BFR浓度的情况对放置在房间内的空气净化器的性能进行了评估。监测结果表明,运行合适的空气净化器可以降低室内空气中气态和颗粒态的BFRs。