Meng Xiangtai, Huang You, Zhao Hongxia, Xie Peizhong, Ma Jianze, Chen Ruyu
State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China.
Org Lett. 2009 Feb 19;11(4):991-4. doi: 10.1021/ol802917d.
A novel domino reaction catalyzed by triphenylphosphine was developed for synthesis of the highly functionalized chroman derivatives. The first example that the gamma-CH(3) of allenoate undergoes cyclization to form chroman derivates was reported.
开发了一种由三苯基膦催化的新型多米诺反应,用于合成高度官能化的色满衍生物。报道了第一例烯丙酸酯的γ-CH(3)发生环化形成色满衍生物的实例。