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废弃电子产品中金属元素的毒性潜力评估:以中国手机为例

Assessment of toxicity potential of metallic elements in discarded electronics: a case study of mobile phones in China.

作者信息

Wu B Y, Chan Y C, Middendorf A, Gu X, Zhong H W

机构信息

EPA Centre, City University of Hong Kong, 83#, Tat Chee Avenue, Kowloon, Hong Kong 852, China.

出版信息

J Environ Sci (China). 2008;20(11):1403-8. doi: 10.1016/s1001-0742(08)62240-8.

Abstract

The electronic waste (e-waste) is increasingly flooding Asia, especially China. E-waste could precipitate a growing volume of toxic input to the local environment if it was not handed properly. This makes the evaluation of environmental impact from electronics an essentially important task for the life cycle assessment (LCA) and the end-of-life management of electronic products. This study presented a quantitative investigation on the environmental performance of typical electronics. Two types of disposed mobile phones (MPs), as a representative of consumer electronics, were evaluated in terms of toxicity potential indicator (TPI) with an assumption of worst-case scenario. It is found that the composition and the percentages of constituents in MPs are similar. More than 20 metallic elements make up 35 wt.%-40 wt.% of the total weight, of which 12 elements are identified to be highly hazardous and 12 are less harmful. With the TPI technique, the environmental performance of Pb is attributed to be 20.8 mg(-1). The total TPIs of metallic elements in the old and new type MP is 255,403 and 127,639 units, respectively, which is equivalent to the effect of releasing 6.14 and 12.28 g Pb into the environment. The average TPI of the old and new type MP is 4.1 and 4.5 mg(-1), respectively, which suggests a similar eco-efficiency per unit mass. The new model of MP is more eco-effective than the old one, which is not due to a reduction in the type of hazardous elements, but rather due to a significant miniaturization of the package with less weight. A single MP can have a considerable toxicity to the environment as referred to Pb, which suggests a major concern for the environmental impact of the total e-waste with a huge quantity and a heavy mass in China.

摘要

电子垃圾(电子废弃物)正日益涌入亚洲,尤其是中国。如果电子垃圾处理不当,可能会导致越来越多的有毒物质进入当地环境。这使得评估电子产品对环境的影响成为生命周期评估(LCA)和电子产品报废管理中一项至关重要的任务。本研究对典型电子产品的环境性能进行了定量调查。作为消费电子产品的代表,两种类型的废旧手机在假设最坏情况的情景下,根据毒性潜力指标(TPI)进行了评估。研究发现,废旧手机的成分和各成分所占百分比相似。20多种金属元素占总重量的35 wt%-40 wt%,其中12种元素被确定为高危害元素,12种危害较小。采用TPI技术,铅的环境性能归因值为20.8 mg(-1)。旧款和新款手机中金属元素的总TPI分别为255,403和127,639单位,这相当于向环境中释放6.14克和12.28克铅的影响。旧款和新款手机的平均TPI分别为4.1和4.5 mg(-1),这表明单位质量的生态效率相似。新款手机比旧款更具生态效益,这并非由于有害元素种类的减少,而是由于包装显著小型化且重量减轻。就铅而言,一部废旧手机可能对环境具有相当大的毒性,这表明在中国,数量巨大、质量沉重的电子垃圾对环境影响令人高度担忧。

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