Synthesis of hierarchical pure ZnO nanostructures with controllable morphology.

Hierarchical pure ZnO nanostructures with controllable morphology were synthesized by two-step oxygen-controlled thermal evaporation method without any catalyst. Zn nanowires with little oxidation were deposited firstly on Si substrates located at the low temperature area at step one. The morphology of hierarchical ZnO nanostructures can be effectively modulated at step two by oxygen flow rate, taking advantage of the controllable oxidation rate of Zn and concentration of ZnO(x) under various oxygen supplies. Transmission electron microscope images and corresponding selected area electron diffraction patterns suggest that low oxygen supplementation causes the epitaxial growth of nanorods from the surface of the Zn nanowire, while high oxygen flow rate will lead to the preferential growth of nanorods along the [001] orientation. Room-temperature photoluminescence measurements demonstrate that the variety of nanostructures can cause the variation of the ultraviolet to green peak intensity ratio, suggesting that the controlled morphologies can be used to modulate the optical properties of ZnO nanostructures.