Narbaitz R M, Karimi-Jashni A
Department of Civil Engineering, University of Ottawa, Ottawa, Ontario, Canada.
Environ Technol. 2009 Jan;30(1):27-36. doi: 10.1080/09593330802422803.
The main objective of this study was to assess the performance of electrochemical regeneration of granular activated carbon via a set of bench-scale experiments using different operating conditions in the regeneration of several different activated carbons loaded with phenol or natural organic matter. The regeneration efficiency can be increased by increasing the charge applied, whether this was achieved by an increase in current or regeneration time. The degree of phenol-adsorption saturation did not significantly affect the regeneration efficiencies. The regeneration efficiencies of the various types of phenol-loaded activated carbon were quite similar despite the differences in their conductivity. The activated carbon exhibiting fully reversible adsorption of phenol had slightly higher regeneration efficiencies than those involving partially irreversible adsorption. Electrochemical regeneration of activated carbon is feasible at a laboratory scale as regeneration efficiencies up to 80% were achieved during electrochemical regeneration of phenol-loaded or natural organic matter-loaded activated carbons.
本研究的主要目的是通过一系列实验室规模的实验,评估在不同操作条件下对几种负载苯酚或天然有机物的不同活性炭进行再生时,颗粒活性炭电化学再生的性能。无论是通过增加电流还是再生时间来增加施加的电荷量,再生效率都可以提高。苯酚吸附饱和度的程度对再生效率没有显著影响。尽管各种负载苯酚的活性炭的电导率不同,但其再生效率相当相似。对苯酚表现出完全可逆吸附的活性炭的再生效率略高于那些涉及部分不可逆吸附的活性炭。在实验室规模下,活性炭的电化学再生是可行的,因为在对负载苯酚或天然有机物的活性炭进行电化学再生时,再生效率可达80%。