Pattacini Roberto, Jie Suyun, Braunstein Pierre
Laboratoire de Chimie de Coordination, Institut de Chimie (UMR 7177 CNRS), Université Louis Pasteur, 4 rue Blaise Pascal, 67070 Strasbourg Cedex, France.
Chem Commun (Camb). 2009 Feb 28(8):890-2. doi: 10.1039/b817728g. Epub 2009 Jan 20.
Both C-Cl bonds of CH(2)Cl(2) are readily activated by CoCl(2) and metallic Zn allowing quantitative methylation of phosphines; unprecedented zwitterionic Co(ii) and Zn(ii) intermediates have been characterized which display alpha-metallated phosphoniums.
二氯甲烷的两个碳氯键都能被二氯化钴和金属锌轻易活化，从而实现膦的定量甲基化；已对前所未有的两性离子钴（II）和锌（II）中间体进行了表征，这些中间体显示出α-金属化鏻盐。
