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Terminal alkyne activation by frustrated and classical Lewis acid/phosphine pairs.

作者信息

Dureen Meghan A, Stephan Douglas W

机构信息

Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada, M5S 3H6.

出版信息

J Am Chem Soc. 2009 Jun 24;131(24):8396-7. doi: 10.1021/ja903650w.

DOI:10.1021/ja903650w
PMID:19485368
Abstract

Frustrated and classical Lewis pairs arising from combinations of Lewis acids and phosphines react with terminal alkynes either via C-H activation forming an alkynylborate salt or by addition to alkyne giving a zwitterionic phosphonium borate.

摘要

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