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脯氨酸-硫脲主客体络合物催化的直接对映选择性羟醛反应。

Direct enantioselective aldol reactions catalyzed by a proline-thiourea host-guest complex.

作者信息

Reis Omer, Eymur Serkan, Reis Barbaros, Demir Ayhan S

机构信息

Department of Chemistry, Middle East Technical University, 06531 Ankara, Turkey.

出版信息

Chem Commun (Camb). 2009 Mar 7(9):1088-90. doi: 10.1039/b817474a. Epub 2009 Jan 7.

Abstract

Proline-thiourea host-guest complex-catalyzed direct enantioselective aldol reactions have been developed, in which the catalytic activities were evaluated in the direct asymmetric aldol reactions of various aromatic aldehydes and cyclohexanone.

摘要

脯氨酸-硫脲主客体复合物催化的直接对映选择性羟醛缩合反应已被开发出来,其中在各种芳香醛与环己酮的直接不对称羟醛缩合反应中评估了催化活性。

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