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Photocatalytic printing of inorganic nanopatterns via poly(styrene-block-carbosilane) copolymer thin films on titania substrates.

作者信息

Peng Juan, Garcia Marcos Alejandra, Jeong Seong-Jun, Frey Holger, Kim Dong Ha

机构信息

The Key Laboratory of Molecular Engineering of Polymers, Ministry of Education, Department of Macromolecular Science, Fudan University, Shanghai 200433, China.

出版信息

Chem Commun (Camb). 2009 Mar 7(9):1091-3. doi: 10.1039/b816398g. Epub 2009 Jan 6.

DOI:10.1039/b816398g
PMID:19225646
Abstract

Well-defined, ordered arrays of nanoscale depressions were obtained in linear-brush-type polystyrene-block-polycarbosilane (PS-b-PCS) diblock copolymer thin films by acetone vapor annealing and silica nanodot arrays were directly obtained from such thin films deposited on a titania substrate by one-step exposure to UV light as a result of transformation of the PCS units to silica, driven by the photocatalytic activity of titania concurrent with removal of the organic matrix.

摘要

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