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两亲嵌段共聚物反胶束纳米模板辅助下分级金属纳米粒子/ZnO 薄膜杂化纳米结构的合成及光催化性能

Synthesis and photocatalytic properties of hierarchical metal nanoparticles/ZnO thin films hetero nanostructures assisted by diblock copolymer inverse micellar nanotemplates.

机构信息

Department of Chemistry and Nano Science, Ewha Womans University, 11-1 Daehyun-Dong, Seodaemun-Gu, Seoul 120-750, Republic of Korea.

出版信息

J Colloid Interface Sci. 2010 May 1;345(1):125-30. doi: 10.1016/j.jcis.2010.01.040. Epub 2010 Jan 18.

Abstract

Metal dot-on-ZnO type hierarchical nanostructures composed of ordered arrays of noble metal nanoparticles with controlled areal density, prepared from poly(styrene-block-vinyl pyridine) diblock copolymer inverse micelles loaded with metal precursors, on sol-gel process based approximately 48 nm thick ZnO thin films exhibit enhanced photocatalytic activities compared with pure ZnO thin films in terms of photodegradation of methylene blue.

摘要

金属点-氧化锌型分级纳米结构由有序排列的贵金属纳米粒子阵列组成,其面密度可控,由负载金属前驱体的聚苯乙烯-嵌段-乙烯基吡啶两亲性嵌段共聚物反胶束制备,在溶胶-凝胶工艺上制备约 48nm 厚的 ZnO 薄膜,在光降解亚甲基蓝方面表现出比纯 ZnO 薄膜更高的光催化活性。

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