Seo Jung Hwa, Jin Youngeup, Brzezinski Jacek Z, Walker Bright, Nguyen Thuc-Quyen
Center for Polymers and Organic Solids, Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA 93106, USA.
Chemphyschem. 2009 May 11;10(7):1023-7. doi: 10.1002/cphc.200800751.
Molecular design: The electronic structure of conjugated polyelectrolytes as a function of ionization potential (IP) and electron affinity (EA) is determined using X-ray absorption and emission spectroscopy (see figure). Different functional groups give rise to dissimilar transport gaps and exciton binding energies.
利用X射线吸收和发射光谱法确定共轭聚电解质的电子结构与电离势(IP)和电子亲和势(EA)的函数关系(见图)。不同的官能团会产生不同的传输能隙和激子结合能。