稳定的双（二异丙基氨基）环丙烯叉（BAC）作为过渡金属配合物的配体。
Stable Bis(diisopropylamino)cyclopropenylidene (BAC) as Ligand for Transition Metal Complexes.
作者信息
Kuchenbeiser Glenn, Donnadieu Bruno, Bertrand Guy
机构信息
UCR-CNRS Joint Research Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403, USA.
出版信息
J Organomet Chem. 2008 Mar 1;693(5):899-904. doi: 10.1016/j.jorganchem.2007.11.056.
Abstract
Several nickel(0), palladium(II), and rhodium(I) complexes have been prepared using for the first time the stable bis(diisopropylamino)cyclopropenylidene (BAC). Based on single crystal X-ray diffraction studies and spectroscopic data, the structural and electronic properties of these complexes are discussed. Moreover, their similarities and differences with the analogous NHC complexes are emphasized.
摘要
首次使用稳定的双（二异丙基氨基）环丙烯叉（BAC）制备了几种零价镍、二价钯和一价铑配合物。基于单晶X射线衍射研究和光谱数据，讨论了这些配合物的结构和电子性质。此外，还强调了它们与类似NHC配合物的异同。
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本文引用的文献
1
N-heterocyclic carbenes: a new concept in organometallic catalysis.N-杂环卡宾：有机金属催化中的一个新概念。
Angew Chem Int Ed Engl. 2002 Apr 15;41(8):1290-309. doi: 10.1002/1521-3773(20020415)41:8<1290::aid-anie1290>3.0.co;2-y.
2
A stable chiral diaminocyclopropenylidene.
Chem Commun (Camb). 2007 Sep 21(35):3661-3. doi: 10.1039/b706708a. Epub 2007 Jun 25.
3
Carbene activation of P4 and subsequent derivatization.卡宾对P4的活化及后续衍生化反应。
Angew Chem Int Ed Engl. 2007;46(37):7052-5. doi: 10.1002/anie.200703055.
4
Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes.通过金催化的掩蔽卡宾与亚乙烯基的交叉偶联生成丙二烯。
Proc Natl Acad Sci U S A. 2007 Aug 21;104(34):13569-73. doi: 10.1073/pnas.0705809104. Epub 2007 Aug 13.
5
Synthesis and reactivity of olefin metathesis catalysts bearing cyclic (alkyl)(amino)carbenes.含环状（烷基）（氨基）卡宾的烯烃复分解催化剂的合成与反应活性
Angew Chem Int Ed Engl. 2007;46(38):7262-5. doi: 10.1002/anie.200702085.
6
Cyclopropenylidene carbene ligands in palladium C-C coupling catalysis.
Chem Commun (Camb). 2007 Jul 14(26):2704-6. doi: 10.1039/b702827j. Epub 2007 Apr 17.
7
Facile splitting of hydrogen and ammonia by nucleophilic activation at a single carbon center.通过单个碳中心的亲核活化实现氢气和氨的简便裂解
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8
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N-heterocyclic carbenes as organocatalysts.作为有机催化剂的氮杂环卡宾
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