Adams J M, Olmsted P D
Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge, CB3 0HE, United Kingdom.
Phys Rev Lett. 2009 Feb 13;102(6):067801. doi: 10.1103/PhysRevLett.102.067801. Epub 2009 Feb 12.
Recent experiments on entangled polymer solutions may indicate a constitutive instability, and have led some to question the validity of existing constitutive models. We use a modern constitutive model, the Rolie-Poly model plus a solvent viscosity, and show that (i) this simple class of models captures instability, (ii) shear banding phenomena is observable for weakly stable fluids in flow geometries with sufficiently inhomogeneous total stress, and (iii) transient phenomena exhibit inhomogeneities similar to shear banding, even for weakly stable fluids.
近期关于缠结聚合物溶液的实验可能表明存在本构不稳定性,这使得一些人对现有本构模型的有效性产生质疑。我们使用一种现代本构模型,即Rolie-Poly模型加上溶剂粘度,并表明:(i)这类简单模型能够捕捉到不稳定性;(ii)在总应力足够不均匀的流动几何形状中,对于弱稳定流体,剪切带现象是可观测的;(iii)即使对于弱稳定流体,瞬态现象也表现出与剪切带相似的不均匀性。