Butcher Robert T, Novoa Juan J, Ribas-Ariño Jordi, Sandvik Anders W, Turnbull Mark M, Landee Christopher P, Wells Brian M, Awwadi Firas F
Carlson School of Chemistry and Biochemistry, Clark University, 950 Main Street, Worcester, MA 01610, USA.
Chem Commun (Camb). 2009 Mar 21(11):1359-61. doi: 10.1039/b819894b. Epub 2009 Feb 12.
An unprecedented antiferromagnetic exchange of -234 K in Cu(2,5-dimethylpyrazine)Br(2) is shown experimentally and theoretically to propagate via through-space interactions between Br ions rather than through-bond interactions.
实验和理论表明，在Cu(2,5 - 二甲基吡嗪)Br₂中，一种前所未有的 - 234K反铁磁交换是通过溴离子之间的空间相互作用而非成键相互作用进行传播的。
