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A systematic approach to the generation of long-lived metal alkane complexes: combined IR and NMR study of (Tp)Re(CO)2(cyclopentane).

作者信息

Duckett Simon B, George Michael W, Jina Omar S, Matthews Steven L, Perutz Robin N, Sun Xue-Zhong, Vuong Khuong Q

机构信息

Department of Chemistry, University of York, Heslington, York, UK YO10 5DD.

出版信息

Chem Commun (Camb). 2009 Mar 21(11):1401-3. doi: 10.1039/b819671k. Epub 2009 Jan 21.

DOI:10.1039/b819671k
PMID:19259601
Abstract

Short wavelength photolysis of (Tp)Re(CO)(3) (Tp = tris(pyrazol-1-yl)borate) at low-temperature in cyclopentane yielded (Tp)Re(CO)(2)(cyclopentane), an alkane complex with three nitrogen ligands that was characterised by NMR spectroscopy.

摘要

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