通过氢键导向自组装合理构建二维和三维博罗梅安排列有机晶体。
Rational construction of 2D and 3D borromean arrayed organic crystals by hydrogen-bond-directed self-assembly.
作者信息
Men Yong-Biao, Sun Junliang, Huang Zhi-Tang, Zheng Qi-Yu
机构信息
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
出版信息
Angew Chem Int Ed Engl. 2009;48(16):2873-6. doi: 10.1002/anie.200806198.
PMID:19283799
Abstract
Borromean organic networks: The rigid and trigonal pyramidal molecule, 1,3,5-tris(4-carboxyphenyl)adamantane (TCA), self-assembles into a 2D Borromean linked network by hydrogen bonds. Different linkers (methanol, phenazine, 4,4'-bipyridine, and 4,4'-azopyridine) result in more complex Borromean networks or a 3D polycatenation network.
摘要
博罗梅安有机网络
刚性三角锥分子1,3,5-三（4-羧基苯基）金刚烷（TCA）通过氢键自组装成二维博罗梅安连接网络。不同的连接体（甲醇、吩嗪、4,4'-联吡啶和4,4'-偶氮吡啶）会导致形成更复杂的博罗梅安网络或三维多连环网络。
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