Spinicelli Piernicola, Mahler Benoit, Buil Stéphanie, Quélin Xavier, Dubertret Benoit, Hermier Jean-Pierre
Laboratoire Kastler Brossel, Ecole normale supérieure, Université Pierre et Marie Curie, CNRS UMR8552, 24 rue Lhomond 75231 Paris, France.
Chemphyschem. 2009 Apr 14;10(6):879-82. doi: 10.1002/cphc.200800827.
Twinkle, twinkle: The blinking of semiconductor colloidal nanocrystals is the main inconvenience of these bright nanoemitters. There are various approaches for obtaining non-blinking nanocrystals, one of which is to grow a thick coat of CdS on the CdSe core (see picture). Applications of this method in the fields of optoelectronic devices, biologic labelling and quantum information processing are discussed.The blinking of semiconductor colloidal nanocrystals is the main inconvenience of these bright nanoemitters. For some years, research on this phenomenon has demonstrated the possibility to progress beyond this problem by suppressing this fluorescence intermittency in various ways. After a brief overview on the microscopic mechanism of blinking, we review the various approaches used to obtain non-blinking nanocrystals and discuss the commitment of this crucial improvement to applications in the fields of optoelectronic devices, biologic labelling and quantum information processing.
半导体胶体纳米晶体的闪烁是这些明亮的纳米发光体的主要不便之处。有多种方法可用于获得不闪烁的纳米晶体,其中一种方法是在CdSe核上生长一层厚厚的CdS涂层(见图)。本文讨论了该方法在光电器件、生物标记和量子信息处理领域的应用。半导体胶体纳米晶体的闪烁是这些明亮的纳米发光体的主要不便之处。多年来,对这一现象的研究表明,通过各种方式抑制这种荧光间歇性,有可能解决这个问题。在简要概述闪烁的微观机制之后,我们回顾了用于获得不闪烁纳米晶体的各种方法,并讨论了这一关键改进对光电器件、生物标记和量子信息处理领域应用的意义。