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Closed and open clamlike structures formed by hydrogen-bonded pairs of cyclotricatechylene anions that contain cationic "meat".

作者信息

Abrahams Brendan F, Fitzgerald Nicholas J, Hudson Timothy A, Robson Richard, Waters Tom

机构信息

School of Chemistry, University of Melbourne, Victoria, Australia.

出版信息

Angew Chem Int Ed Engl. 2009;48(17):3129-32. doi: 10.1002/anie.200805789.

Abstract

Clamming up: The hexaphenolic compound cyclotricatechylene, which has a bowl-shaped cavity, forms clamlike pairs that encapsulate cations (see picture). Variable hydrogen bonding allows two linked cyclotricatechylene clamshells to be in a closed arrangement when smaller cations such Rb(+) or Cs(+) provide the clam meat, whereas larger cations such as NMe(4) (+) and NEt(4) (+) cause the clam to be partially opened.

摘要

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