Haussmann Philip C, Stoddart J Fraser
California NanoSystems Institute, and Department of Chemistry and Biochemistry, University of California, Los Angeles, 405 Hilgard Avenue, Los Angeles, CA 90095-1569, USA.
Chem Rec. 2009;9(2):136-54. doi: 10.1002/tcr.20173.
As the complexity of mechanically interlocked molecular architectures increases, it is important to understand the underlying principles, such as molecular recognition and self-assembly processes, that govern the practice of template-directed synthesis necessary to create these particular compounds. In this review, we explain the importance of dynamic processes in the synthesis of mechanically interlocked compounds. We show how many different dynamic covalent bonds have been used in the synthesis of rotaxanes, catenanes, and other higher-order mechanically interlocked compounds, with the goal of revealing the state of the art in dynamic covalent chemistry.
随着机械互锁分子结构的复杂性增加，理解诸如分子识别和自组装过程等基础原理变得很重要，这些原理支配着合成这些特定化合物所需的模板导向合成实践。在本综述中，我们解释了动态过程在机械互锁化合物合成中的重要性。我们展示了在轮烷、索烃及其他高阶机械互锁化合物的合成中使用了多少种不同的动态共价键，目的是揭示动态共价化学的最新进展。
