通过螺旋胶束的手性印迹制备的介孔二氧化硅实现超分子手性转录与识别。
Supramolecular chiral transcription and recognition by mesoporous silica prepared by chiral imprinting of a helical micelle.
作者信息
Qiu Huibin, Inoue Yoshihisa, Che Shunai
机构信息
School of Chemistry and Chemical Technology, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai, P. R. China.
出版信息
Angew Chem Int Ed Engl. 2009;48(17):3069-72. doi: 10.1002/anie.200900303.
PMID:19309027
Abstract
Let's twist again: The chirality of a helical propeller-like micelle has been memorized by functional groups on the mesopore surface of chiral mesoporous silicas. Such imprinted supramolecular chirality can be transcripted to poly(propiolic acid) sodium salt and tetraphenylporphine tetrasulfonic acid (see picture), and recognized by B-DNA.
摘要
让我们再次扭转
螺旋桨状胶束的手性已被手性介孔二氧化硅中孔表面的官能团所记忆。这种印记超分子手性可以转录到聚（丙炔酸）钠盐和四苯基卟啉四磺酸上（见图），并被B - DNA识别。
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