Synthesis and reactivity of a bis(dimesitylboryl)azaborine and its fluoride sensing ability.
作者信息
Agou Tomohiro, Sekine Masaki, Kobayashi Junji, Kawashima Takayuki
机构信息
Department of Chemistry, Graduate School of Science, The University of Tokyo, Bunkyo-ku, Tokyo, Japan.
出版信息
Chem Commun (Camb). 2009 Apr 14(14):1894-6. doi: 10.1039/b818505k. Epub 2009 Feb 20.
DOI:10.1039/b818505k
PMID:19319437
Abstract
An azaborine bearing two dimesitylboryl groups on its periphery showed very strong light absorption and moderate photo-luminescence emission; the reaction of the title compound with fluoride ion resulted in multi-step fluoride ion complexation on the boron atoms of the dimesitylboryl groups, producing mono- and bisfluoroborates.
摘要
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