一种使用发光CdSe/ZnS量子点的氟化物“开-关”传感器。

An "off-on" sensor for fluoride using luminescent CdSe/ZnS quantum dots.

作者信息

Mulrooney Ray C, Singh Narinder, Kaur Navneet, Callan John F

机构信息

School of Pharmacy and Life Sciences, The Robert Gordon University Aberdeen, Scotland, UKAB10 1FR.

出版信息

Chem Commun (Camb). 2009 Feb 14(6):686-8. doi: 10.1039/b817569a. Epub 2008 Dec 12.

DOI:10.1039/b817569a

PMID:19322422

Abstract

The fluorescence emission of CdSe/ZnS QDs was switched "off" when the native trioctylphosphine oxide ligands were exchanged for 1-(bis(eta(5)-cyclopentadienyl)iron)-methyl-3-(5,7-dimercapto-heptyl)-urea (); importantly, the emission of the resulting conjugate was switched "on" upon addition of fluoride ions.

摘要

当将天然的三辛基氧化膦配体换成1-(双(η(5)-环戊二烯基)铁)-甲基-3-(5,7-二巯基庚基)-脲时，CdSe/ZnS量子点的荧光发射被“关闭”；重要的是，加入氟离子后，所得共轭物的发射被“打开”。