手性双功能磺酰胺催化醛对硝基烯烃的高对映选择性共轭加成反应。
Highly enantioselective conjugate addition of aldehydes to nitroolefins catalyzed by chiral bifunctional sulfamides.
作者信息
Zhang Xue-Jing, Liu Sheng-Ping, Li Xue-Ming, Yan Ming, Chan Albert S C
机构信息
Industrial Institute of Fine Chemicals and Synthetic Drugs, School of Pharmaceutical Sciences, Sun Yat-sen University, Guangzhou 510006, China.
出版信息
Chem Commun (Camb). 2009 Feb 21(7):833-5. doi: 10.1039/b818582d. Epub 2008 Dec 15.
DOI:10.1039/b818582d
PMID:19322457
Abstract
Chiral bifunctional sulfamides were found to be highly efficient organocatalysts for the conjugate addition of aldehydes to nitroolefins in the presence of base additives.
摘要
手性双功能磺酰胺被发现是在碱添加剂存在下醛与硝基烯烃共轭加成反应的高效有机催化剂。
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