Scheer Manfred, Schindler Andrea, Gröger Christian, Virovets Alexander V, Peresypkina Eugenia V
Institut für Anorganische Chemie der Universität Regensburg, 93040 Regensburg, Germany.
Angew Chem Int Ed Engl. 2009;48(27):5046-9. doi: 10.1002/anie.200900342.
The complete encapsulation of ortho-carborane by a fullerene-like building-block system consisting of pentaphosphaferrocene and Cu(I)Cl leads to the formation of the spherical supermolecule C(2)B(10)H(12) section sign[{Cp*Fe(eta(5)-P(5))}(12)(CuCl)(20)]. This product of template-controlled aggregation represents the first example of a carbon-free C(80) analogue possessing icosahedral symmetry.
由五磷铁茂和氯化亚铜（I）组成的类富勒烯构建块体系对邻碳硼烷的完全包封导致形成球形超分子C(2)B(10)H(12)□[{Cp*Fe(η(5)-P(5))}(12)(CuCl)(20)]。这种模板控制聚集的产物代表了具有二十面体对称性的无碳C(80)类似物的首个实例。
