从纳米球到纳米碗。

Brake Helena, Peresypkina Eugenia, Heindl Claudia, Virovets Alexander V, Kremer Werner, Scheer Manfred

Institut für Anorganische Chemie , Universität Regensburg , 93040 Regensburg , Germany . Email:

Novosibirsk State University , Pirogova str. 2 , 630090 Novosibirsk , Russia.

Chem Sci. 2019 Jan 23;10(10):2940-2944. doi: 10.1039/c8sc05471a. eCollection 2019 Mar 14.

Pentaphosphaferrocene [Cp*Fe(η-P)] in combination with Cu(i) halides is capable of a template-directed synthesis of fullerene-like spheres. Herein, we present the use of a triple decker complex as template that leads to the formation of unprecedented 'nano-bowls'. These spherical domes resemble the truncated fullerenes -C and represent a novel spherical arrangement in the chemistry of spherical molecules.

五磷代二茂铁[Cp*Fe(η-P)]与卤化亚铜结合能够进行模板导向的类富勒烯球体合成。在此，我们展示了使用一种三层夹心配合物作为模板，从而导致形成前所未有的“纳米碗”。这些球形穹顶类似于截顶富勒烯-C，代表了球形分子化学中一种新颖的球形排列。