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通过溶液法制备的具有高导电性和超疏水性的柔性碳纳米管-聚合物复合薄膜。

Flexible carbon nanotube-polymer composite films with high conductivity and superhydrophobicity made by solution process.

作者信息

Luo Chan, Zuo Xiaolei, Wang Lei, Wang Ergang, Song Shiping, Wang Jing, Wang Jian, Fan Chunhai, Cao Yong

机构信息

Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Key Laboratory of Specially Functional Materials, Ministry of Education, Guangzhou 510640, PR China.

出版信息

Nano Lett. 2008 Dec;8(12):4454-8. doi: 10.1021/nl802411d.

Abstract

CNT/Nafion nanocomposite film made by solution process exhibits high conductivity and superhydrophobicity. The highest water contact angle reaches 165.3 +/- 1.9 degrees. The wettability of the film can be controlled by simply varying the filtering rate and the content ratio of Nafion to CNT. We also develop a novel optical method to directly observe the air-solid-liquid interface for the first time. The extraordinary mechanical strength provided by the polymer helps the film retain its conductivity and superhydrobicity after 1000 bending cycles.

摘要

通过溶液法制备的碳纳米管/全氟磺酸(CNT/Nafion)纳米复合薄膜具有高导电性和超疏水性。最高水接触角达到165.3±1.9度。通过简单改变过滤速率以及全氟磺酸与碳纳米管的含量比,就可以控制薄膜的润湿性。我们还首次开发了一种新颖的光学方法来直接观察气-固-液界面。聚合物提供的非凡机械强度帮助薄膜在经过1000次弯曲循环后仍保持其导电性和超疏水性。

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