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一种嵌入活性炭-纳米管偏振器的电极与液晶取向

An active carbon-nanotube polarizer-embedded electrode and liquid-crystal alignment.

作者信息

Kim Tae Hyung, Park Jong Gil, Kim Yul Ki, Lim Young Jin, Kang Jae-Wook, Kim Eun Sung, Kwon Jeong Yong, Lee Young Hee, Lee Seung Hee

机构信息

Graduate School of Flexible & Printable Electronics, Jeonbuk National University, Jeonju 54896, South Korea.

出版信息

Nanoscale. 2020 Sep 14;12(34):17698-17702. doi: 10.1039/d0nr02276d. Epub 2020 Jun 25.

Abstract

We report a method for constructing an active optical polarizer using an aligned carbon nanotube (CNT) sheet that is flexible, bendable, transparent, conductive, and also serves to anchor liquid-crystal (LC) molecules. A horizontally aligned CNT sheet was obtained by mechanical stretching from a vertically grown CNT forest, which was then transferred onto a substrate. A liquid polymer was infiltrated into the CNT sheet followed by UV curing, while a part of the CNT sheet was still exposed on the film surface without polymer coating. The polymer-embedded CNT sheet (P-ECS) film with 10 layers of CNT sheets exhibited a good polarization efficiency of 87%, a sheet resistance of 340 Ω□, and excellent ability to align LC molecules. The high stability of the P-ECS film was confirmed from the very low variation of sheet resistance (2%) and transmittance (10%) observed during a bending test of 1000 cycles. In addition, a twisted nematic LC device constructed using the P-ECS films shows a good bright-dark switching performance. The P-ECS film functions simultaneously as a transparent electrode, a film-type polarizer, and a LC alignment layer, demonstrating the multi-functionality of the active CNT film. This study thus highlights a wide range of possible applications for active polarizers and flexible displays.

摘要

我们报道了一种使用排列的碳纳米管(CNT)片构建有源光学偏振器的方法,该碳纳米管片具有柔性、可弯曲、透明、导电的特性,还可用于锚定液晶(LC)分子。通过对垂直生长的碳纳米管森林进行机械拉伸获得水平排列的碳纳米管片,然后将其转移到基板上。将液态聚合物渗透到碳纳米管片中,随后进行紫外线固化,而碳纳米管片的一部分仍暴露在膜表面,没有聚合物涂层。具有10层碳纳米管片的聚合物嵌入碳纳米管片(P-ECS)膜表现出87%的良好偏振效率、340Ω□的薄层电阻以及出色的液晶分子排列能力。在1000次循环的弯曲测试中观察到薄层电阻(2%)和透射率(10%)的变化非常小,证实了P-ECS膜的高稳定性。此外,使用P-ECS膜构建的扭曲向列型液晶器件显示出良好的亮暗切换性能。P-ECS膜同时作为透明电极、薄膜型偏振器和液晶排列层发挥作用,展示了有源碳纳米管膜的多功能性。因此,这项研究突出了有源偏振器和柔性显示器的广泛潜在应用。

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