金属有机骨架材料作为催化剂。
Metal-organic framework materials as catalysts.
作者信息
Lee JeongYong, Farha Omar K, Roberts John, Scheidt Karl A, Nguyen SonBinh T, Hupp Joseph T
机构信息
Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, USA.
出版信息
Chem Soc Rev. 2009 May;38(5):1450-9. doi: 10.1039/b807080f. Epub 2009 Mar 17.
A critical review of the emerging field of MOF-based catalysis is presented. Discussed are examples of: (a) opportunistic catalysis with metal nodes, (b) designed catalysis with framework nodes, (c) catalysis by homogeneous catalysts incorporated as framework struts, (d) catalysis by MOF-encapsulated molecular species, (e) catalysis by metal-free organic struts or cavity modifiers, and (f) catalysis by MOF-encapsulated clusters (66 references).
本文对基于金属有机框架（MOF）的催化这一新兴领域进行了批判性综述。讨论的例子包括：（a）金属节点的机会主义催化，（b）框架节点的设计催化，（c）作为框架支柱掺入的均相催化剂的催化，（d）MOF封装的分子物种的催化，（e）无金属有机支柱或腔修饰剂的催化，以及（f）MOF封装的簇的催化（66篇参考文献）。
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