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均匀剪切系统的非平衡模式耦合理论

Nonequilibrium mode-coupling theory for uniformly sheared systems.

作者信息

Chong Song-Ho, Kim Bongsoo

机构信息

Institute for Molecular Science, Okazaki 444-8585, Japan.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2009 Feb;79(2 Pt 1):021203. doi: 10.1103/PhysRevE.79.021203. Epub 2009 Feb 20.

Abstract

We develop a nonequilibrium mode-coupling theory for uniformly sheared systems starting from microscopic, thermostatted Sllod equations of motion. Our theory aims at describing stationary-state properties including rheological ones of sheared systems, and this is accomplished via two steps. First, a set of self-consistent equations is formulated based on the projection-operator formalism and on the mode-coupling approach for the transient density correlators which measure the correlations between the density fluctuations in the initial equilibrium state and the ones at later times after the shearing force is turned on. The transient time-correlation function formalism is then used which, combined with the mode-coupling approximation, expresses stationary-state properties in terms of the transient density correlators. A detailed comparison of our theory is also presented with the related mode-coupling theory which is based on the Smoluchowski equation for Brownian particles under stationary shearing.

摘要

我们从微观的、恒温的斯勒德运动方程出发,为均匀剪切系统发展了一种非平衡模式耦合理论。我们的理论旨在描述稳态性质,包括剪切系统的流变性质,这通过两个步骤来实现。首先,基于投影算符形式主义和用于瞬态密度关联函数的模式耦合方法,制定一组自洽方程,这些瞬态密度关联函数测量初始平衡态下的密度涨落与剪切力开启后稍后时刻的密度涨落之间的相关性。然后使用瞬态时间关联函数形式主义,它与模式耦合近似相结合,根据瞬态密度关联函数来表达稳态性质。我们还将我们的理论与基于平稳剪切下布朗粒子的斯莫卢霍夫斯基方程的相关模式耦合理论进行了详细比较。

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