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来自大理白前的四种新寡糖和两种新糖苷的完整氢谱和碳谱归属

Complete 1H and 13C NMR assignments of four new oligosaccharides and two new glycosides from Periploca forrestii.

作者信息

Feng Jiaquan, Zhao Weimin

机构信息

Shanghai Institute of Materia Medica, Shanghai Institutes for Biological Sciences, Chinese Academy of Sciences, Shanghai 201203, People's Republic of China.

出版信息

Magn Reson Chem. 2009 Aug;47(8):701-5. doi: 10.1002/mrc.2440.

Abstract

Four new oligosaccharides (1-4), one new pregnane glycoside (5), and one new cardiac glycoside (6) were isolated from the roots of Periploca forrestii Schltr. (Asclepiadaceae), a traditional Chinese medicine used for the treatment of rheumatoid arthritis and wounds. Their structures were characterized on the basis of extensive analysis of NMR (1H, 13C NMR, 1H-1H COSY, HSQC, HMBC, TOCSY and ROESY) spectra.

摘要

从用于治疗类风湿性关节炎和伤口的传统中药黑骨藤(萝摩科)的根中分离出四种新的寡糖(1-4)、一种新的孕烷糖苷(5)和一种新的强心苷(6)。通过对核磁共振(1H、13C NMR、1H-1H COSY、HSQC、HMBC、TOCSY和ROESY)光谱的广泛分析对它们的结构进行了表征。

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