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利用磁性纳米粒子从溶液中去除和回收吖啶橙。

Removal and recovery of acridine orange from solutions by use of magnetic nanoparticles.

作者信息

Qadri Shahnaz, Ganoe Ashley, Haik Yousef

机构信息

Center of Research Excellence in Nanobiosciences, University of North Carolina at Greensboro, Greensboro, NC 27402, United States.

出版信息

J Hazard Mater. 2009 Sep 30;169(1-3):318-23. doi: 10.1016/j.jhazmat.2009.03.103. Epub 2009 Mar 31.

Abstract

Here we report a separation of a cationic dye, acridine orange (AO), by use of magnetic nanoparticles (gamma-Fe(2)O(3)). The particles were showed to capture 98% of the dye within the first 20 min of contact time. The maximum sorption capacity of the magnetic nanoparticles (MNPs) for AO was 59mg/g. The sorption isotherms fit well with the Freundlich model. The sorption kinetics fits well the pseudo-second-order rate equation model. 60-90% dye recovery was achieved by rotary evaporating the dye bearing nanoparticles in acetone. The nanoparticles were recycled for additional dye removal.

摘要

在此我们报告了使用磁性纳米颗粒(γ-Fe₂O₃)分离阳离子染料吖啶橙(AO)的方法。结果表明,在接触的前20分钟内,这些颗粒能够捕获98%的染料。磁性纳米颗粒(MNPs)对AO的最大吸附容量为59mg/g。吸附等温线与弗伦德利希模型拟合良好。吸附动力学与伪二级速率方程模型拟合良好。通过在丙酮中旋转蒸发负载染料的纳米颗粒,实现了60 - 90%的染料回收率。这些纳米颗粒可循环使用以进一步去除染料。

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