Qadri Shahnaz, Ganoe Ashley, Haik Yousef
Center of Research Excellence in Nanobiosciences, University of North Carolina at Greensboro, Greensboro, NC 27402, United States.
J Hazard Mater. 2009 Sep 30;169(1-3):318-23. doi: 10.1016/j.jhazmat.2009.03.103. Epub 2009 Mar 31.
Here we report a separation of a cationic dye, acridine orange (AO), by use of magnetic nanoparticles (gamma-Fe(2)O(3)). The particles were showed to capture 98% of the dye within the first 20 min of contact time. The maximum sorption capacity of the magnetic nanoparticles (MNPs) for AO was 59mg/g. The sorption isotherms fit well with the Freundlich model. The sorption kinetics fits well the pseudo-second-order rate equation model. 60-90% dye recovery was achieved by rotary evaporating the dye bearing nanoparticles in acetone. The nanoparticles were recycled for additional dye removal.
在此我们报告了使用磁性纳米颗粒(γ-Fe₂O₃)分离阳离子染料吖啶橙(AO)的方法。结果表明,在接触的前20分钟内,这些颗粒能够捕获98%的染料。磁性纳米颗粒(MNPs)对AO的最大吸附容量为59mg/g。吸附等温线与弗伦德利希模型拟合良好。吸附动力学与伪二级速率方程模型拟合良好。通过在丙酮中旋转蒸发负载染料的纳米颗粒,实现了60 - 90%的染料回收率。这些纳米颗粒可循环使用以进一步去除染料。