McCann Donald F, McGann Jason M, Parks Jesse M, Frankel David J, da Cunha Mauricio Pereira, Vetelino John F
Laboratory for Surface Science and Technology, University of Maine, Orono, ME, USA.
IEEE Trans Ultrason Ferroelectr Freq Control. 2009 Apr;56(4):779-87. doi: 10.1109/TUFFC.2009.1100.
The most popular bulk acoustic wave (BAW) sensor is the quartz crystal microbalance (QCM), which has electrodes on both the top and bottom surfaces of an AT-cut quartz wafer. In the QCM, the exciting electric field is primarily perpendicular to the crystal surface, resulting in a thickness field excitation (TFE) of a resonant temperature compensated transverse shear mode (TSM). The TSM, however, can also be excited by lateral field excitation (LFE) in which electrodes are placed on one side of the wafer leaving a bare sensing surface exposed directly to a liquid or a chemi/bio selective layer allowing the detection of both mechanical and electrical property changes caused by a target analyte. The use of LFE sensors has motivated an investigation to identify other piezoelectric crystal orientations that can support temperature-compensated TSMs and operate efficiently at high frequencies resulting in increased sensitivity. In this work, theoretical search and experimental measurements are performed to identify the existence of high-frequency temperature-compensated TSMs in LiTaO(3). Prototype LFE LiTaO(3) sensors were fabricated and found to operate at frequencies in excess of 1 GHz and sensitively detect viscosity, conductivity, and dielectric constant changes in liquids.
最流行的体声波(BAW)传感器是石英晶体微天平(QCM),它在AT切割石英晶片的上下表面都有电极。在QCM中,激励电场主要垂直于晶体表面,从而产生谐振温度补偿横向剪切模式(TSM)的厚度场激励(TFE)。然而,TSM也可以通过横向场激励(LFE)来激发,在横向场激励中,电极放置在晶片的一侧,使裸露的传感表面直接暴露于液体或化学/生物选择层,从而能够检测目标分析物引起的机械和电学性质变化。LFE传感器的使用促使人们开展研究,以确定其他能够支持温度补偿TSM并在高频下高效运行从而提高灵敏度的压电晶体取向。在这项工作中,进行了理论搜索和实验测量,以确定钽酸锂(LiTaO₃)中高频温度补偿TSM的存在。制作了LFE钽酸锂(LiTaO₃)传感器原型,发现其工作频率超过1 GHz,并且能够灵敏地检测液体中的粘度、电导率和介电常数变化。