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通过静电纺丝制备的嵌入银纳米颗粒的Tb3+/Ce3+共掺杂NaYF4/PVP纳米纤维的光致发光

Photoluminescence of Ag nanoparticle embedded Tb3+/Ce3+ codoped NaYF4/PVP nanofibers prepared by electrospinning.

作者信息

Dong Guoping, Liu Xiaofeng, Xiao Xiudi, Qian Bin, Ruan Jian, Ye Song, Yang Hucheng, Chen Danping, Qiu Jianrong

机构信息

State Key Laboratory of High Field Laser Physics, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Jiading District, Shanghai 201800, People's Republic of China.

出版信息

Nanotechnology. 2009 Feb 4;20(5):055707. doi: 10.1088/0957-4484/20/5/055707. Epub 2009 Jan 12.

Abstract

Ag nanoparticle embedded NaYF(4):0.05Tb.xCe/PVP (PVP stands for poly(vinyl pyrrolidone)) composite nanofibers have been prepared by electrospinning. A field emission scanning electron microscope and x-ray diffraction have been utilized to characterize the size, morphology and structure of the as-prepared electrospun nanofibers. Obvious photoluminescence (PL) of NaYF(4):0.05Tb.0.05Ce/PVP electrospun nanofibers due to the efficient energy transfer from Ce(3+) to Tb(3+) ions is observed. The PL intensity of the electrospun nanofibers decreases gradually with the addition of Ag nanoparticles. No obvious surface plasmon resonance enhanced luminescence is observed. The reasons for the weakening of the emission intensity with the addition of Ag nanoparticles have also been discussed in this work.

摘要

通过静电纺丝制备了嵌入银纳米颗粒的NaYF₄:0.05TbₓCe/PVP(PVP代表聚乙烯吡咯烷酮)复合纳米纤维。利用场发射扫描电子显微镜和X射线衍射对所制备的静电纺纳米纤维的尺寸、形态和结构进行了表征。观察到NaYF₄:0.05Tb₀.05Ce/PVP静电纺纳米纤维由于Ce(³⁺)到Tb(³⁺)离子的有效能量转移而产生明显的光致发光(PL)。随着银纳米颗粒的加入,静电纺纳米纤维的PL强度逐渐降低。未观察到明显的表面等离子体共振增强发光。本文还讨论了添加银纳米颗粒后发射强度减弱的原因。

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