Curtis-Long Marcus J, Aye Yimon
Woodview, Nafferton, East Yorkshire, YO25 4JP, UK.
Chemistry. 2009;15(22):5402-16. doi: 10.1002/chem.200900337.
An up-to-date in-depth review of the current virtues and limitations in the realm of carbonyl addition reactions with allenyl-, propargyl-, and vinylsilicon reagents, encompassing numerous practical as well as pedagogical principles is presented. Comparisons of chemo-, regio-, and stereoselectivity and reactivity are drawn. Synthetic applications and challenges associated with each class of organosilane are discussed threading together the prospects of these green carbanion surrogates.
本文对使用烯丙基硅试剂、炔丙基硅试剂和乙烯基硅试剂进行羰基加成反应领域的当前优点和局限性进行了最新的深入综述，涵盖了许多实用和教学原则。文中对化学选择性、区域选择性和立体选择性以及反应活性进行了比较。讨论了与每类有机硅相关的合成应用和挑战，并梳理了这些绿色碳负离子替代物的前景。
