铜（I）配合物与 N-氧化物反应的中间体：从形成稳定的加合物到氧转移。
Intermediates in reactions of copper(I) complexes with N-oxides: from the formation of stable adducts to oxo transfer.
机构信息
Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota 55455, USA.
出版信息
Inorg Chem. 2009 Jul 20;48(14):6323-5. doi: 10.1021/ic900435p.
Abstract
Reactions of copper(I) complexes of bidentate N-donor supporting ligands with pyridine- and trimethylamine-N-oxides or PhIO were explored. Key results include the identification of novel copper(I) N-oxide adducts, aryl substituent hydroxylation, and bis(mu-oxo)dicopper complex formation via a route involving oxo transfer.
摘要
研究了双齿 N-供体配位体与吡啶和三甲胺-N-氧化物或 PhIO 的铜(I)配合物的反应。主要结果包括新型铜(I)N-氧化物加合物的鉴定、芳基取代基的羟化以及通过涉及氧转移的途径形成双(μ-氧)二铜配合物。
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