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铜（I）配合物与 N-氧化物反应的中间体：从形成稳定的加合物到氧转移。

Intermediates in reactions of copper(I) complexes with N-oxides: from the formation of stable adducts to oxo transfer.

机构信息

Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota 55455, USA.

出版信息

Inorg Chem. 2009 Jul 20;48(14):6323-5. doi: 10.1021/ic900435p.

DOI:10.1021/ic900435p
PMID:19425587
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2878392/
Abstract

Reactions of copper(I) complexes of bidentate N-donor supporting ligands with pyridine- and trimethylamine-N-oxides or PhIO were explored. Key results include the identification of novel copper(I) N-oxide adducts, aryl substituent hydroxylation, and bis(mu-oxo)dicopper complex formation via a route involving oxo transfer.

摘要

研究了双齿 N-供体配位体与吡啶和三甲胺-N-氧化物或 PhIO 的铜(I)配合物的反应。主要结果包括新型铜(I)N-氧化物加合物的鉴定、芳基取代基的羟化以及通过涉及氧转移的途径形成双(μ-氧)二铜配合物。

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本文引用的文献

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Inorg Chem. 2009 May 18;48(10):4514-23. doi: 10.1021/ic9002466.
2
Generating Cu(II)-oxyl/Cu(III)-oxo species from Cu(I)-alpha-ketocarboxylate complexes and O2: in silico studies on ligand effects and C-H-activation reactivity.从Cu(I)-α-酮羧酸盐配合物和O₂生成Cu(II)-氧基/Cu(III)-氧代物种：关于配体效应和C-H活化反应性的计算机模拟研究
Chemistry. 2009;15(19):4886-95. doi: 10.1002/chem.200802338.
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Copper-hydroperoxo-mediated N-debenzylation chemistry mimicking aspects of copper monooxygenases.铜-氢过氧介导的N-脱苄基化学模拟单加氧铜酶的某些方面。
Inorg Chem. 2008 Oct 6;47(19):8736-47. doi: 10.1021/ic800617m. Epub 2008 Sep 11.
4
Synthesis and characterization of 3-cyano- and 3-nitroformazans, nitrogen-rich analogues of beta-diketimine ligands.β-二酮亚胺配体的富氮类似物3-氰基和3-硝基甲臜的合成与表征
Inorg Chem. 2008 Feb 18;47(4):1279-86. doi: 10.1021/ic7019445. Epub 2008 Jan 25.
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Transition metal complexes of 3-cyano- and 3-nitroformazans.3-氰基和3-硝基甲臜的过渡金属配合物
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