银（I）介导的焦膦酸酯形成与乙腈的碳-碳键裂解。
Ag(I)-mediated formation of pyrophosphonate coupled with C-C bond cleavage of acetonitrile.
作者信息
Guo Li-Rong, Bao Song-Song, Li Yi-Zhi, Zheng Li-Min
机构信息
State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, PR China.
出版信息
Chem Commun (Camb). 2009 May 28(20):2893-5. doi: 10.1039/b902162k. Epub 2009 Apr 6.
DOI:10.1039/b902162k
PMID:19436901
Abstract
A general approach to obtain pyrophosphonates is achieved by reacting arylphosphonic acids with AgNO(3) in CH(3)CN under solvothermal conditions; the process is coupled with the C-C bond cleavage of acetonitrile and the formation of novel complexes Ag(n)(RPO(2)(O)O(2)PR)(m); the mechanism of the process is proposed.
摘要
通过在溶剂热条件下使芳基膦酸与硝酸银在乙腈中反应，实现了一种获得焦膦酸盐的通用方法；该过程伴随着乙腈的C-C键断裂以及新型配合物Ag(n)(RPO(2)(O)O(2)PR)(m)的形成；并提出了该过程的机理。
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