The anomalous solid state decomposition of ammonium dinitramide: a matter of surface polarization.
作者信息
Rahm Martin, Brinck Tore
机构信息
Physical Chemistry, School of Chemical Science and Engineering, Royal Institute of Technology (KTH), Stockholm, Sweden.
出版信息
Chem Commun (Camb). 2009 May 28(20):2896-8. doi: 10.1039/b900915a. Epub 2009 Apr 6.
DOI:10.1039/b900915a
PMID:19436902
Abstract
Polarized dinitramide anions on the surface of solid ammonium dinitramide (ADN) have a decomposition barrier that is reduced by 16 kcal mol(-1) and explain the anomalous solid state decomposition of ADN.
摘要
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