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[电感耦合等离子体发射光谱法测定葡萄酒中的23种微量元素]

[Determination of 23 trace elements in wines by ICP-AES].

作者信息

Wan Yi-Qun, Pan Feng-Qin, Liu Ying-Xia, Yu Yong

机构信息

The Key Laboratory of Food Science of Ministry of Education, Nanchang University, Nanchang 330047, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2009 Feb;29(2):499-503.

PMID:19445237
Abstract

In the present paper, the contents of trace elements As, Ba, Co, Ni, Cu, Be, Sr, Cr, Mn, Li, P, Se, Pb, Bi, Cd, B, Zn, Mg, Fe, K, Na, Ca and Al in nineteen wines produced in Jiangxi province were determined by using inductively coupled plasma-atomic emission spectrometry (ICP-AES). The differentiation in the trace elements between wines was studied in terms of different producing regions, as well as different alcoholic degrees and qualities from the same manufacturer. The experimental results indicated that with the samples cleared up completely by a small quantity of nitric acid the method could satisfy the request of ICP-AES analysis. The relative standard deviations of the method were between 0 and 5.81%, and the recovery rates were between 90.5% and 107.6%. The measuring method provided better accuracy and precision, and the trace elements showed definite differences between wines produced from different regions and with different alcoholic degrees and qualities from the same manufacturer. For instance, there is small amount of element Bi only in the wines of A factory, the content of elements Co, P and Se is higher in the wines of B factory, the content of elements Cu, Fe, K is higher in the wines of C factory, and the content of element Al in the wines of D factory is obviously higher than others. So the research results in this paper provided the theoretical basis for further study of the relationship between wine qualities and trace elements.

摘要

本文采用电感耦合等离子体原子发射光谱法(ICP-AES)测定了江西省产19种葡萄酒中微量元素砷(As)、钡(Ba)、钴(Co)、镍(Ni)、铜(Cu)、铍(Be)、锶(Sr)、铬(Cr)、锰(Mn)、锂(Li)、磷(P)、硒(Se)、铅(Pb)、铋(Bi)、镉(Cd)、硼(B)、锌(Zn)、镁(Mg)、铁(Fe)、钾(K)、钠(Na)、钙(Ca)和铝(Al)的含量。从不同产地以及同一厂家不同酒精度和品质的葡萄酒方面研究了微量元素的差异。实验结果表明,用少量硝酸将样品完全消解后,该方法能满足ICP-AES分析要求。该方法的相对标准偏差在0至5.81%之间,回收率在90.5%至107.6%之间。该测定方法具有较好的准确度和精密度,不同产地以及同一厂家不同酒精度和品质的葡萄酒中微量元素存在一定差异。例如,仅A厂葡萄酒中有少量元素铋(Bi),B厂葡萄酒中元素钴(Co)、磷(P)和硒(Se)的含量较高,C厂葡萄酒中元素铜(Cu)、铁(Fe)、钾(K)的含量较高,D厂葡萄酒中元素铝(Al)的含量明显高于其他厂。因此,本文的研究结果为进一步研究葡萄酒品质与微量元素之间的关系提供了理论依据。

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