Evidence for Pt(II)-based molecular catalysis in the thermal reduction of water into molecular hydrogen.
作者信息
Yamauchi Kosei, Masaoka Shigeyuki, Sakai Ken
机构信息
Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki 6-10-1, Higashi-ku, Fukuoka 812-8581, Japan.
出版信息
J Am Chem Soc. 2009 Jun 24;131(24):8404-6. doi: 10.1021/ja902245e.
PMID:19462999
Abstract
The one-electron-reduced form of methylviologen (MV(+*)), generated in situ by bulk electrolysis of methylviologen (MV(2+)), was for the first time reacted with various Pt(II) complexes in aqueous media without light irradiation to reveal that thermal reduction of water into molecular hydrogen is indeed highly promoted by the Pt(II)-based molecular catalysts.
摘要
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