Kim Youngmin, Hudnall Todd W, Bouhadir Ghenwa, Bourissou Didier, Gabbaï François P
Department of Chemistry, Texas A&M University, College Station, Texas 77843, USA.
Chem Commun (Camb). 2009 Jul 7(25):3729-31. doi: 10.1039/b905232a. Epub 2009 May 27.
In H(2)O-CHCl(3), the phosphonium borane ortho-(Mes(2)B)C(6)H(4)(PMePh(2)) selectively complexes azide anions to afford ortho-(Mes(2)(N(3))B)C(6)H(4)(PMePh(2)) in which the boron-bound azide anion is stabilized by an interaction with the adjacent phosphorus atom.
在H₂O-CHCl₃中，鏻硼烷[邻-(Mes₂B)C₆H₄(PMePh₂)]⁺选择性地与叠氮阴离子络合，生成邻-(Mes₂(N₃)B)C₆H₄(PMePh₂)，其中与硼相连的叠氮阴离子通过与相邻磷原子的相互作用而稳定。
