三（有机锡基）甲烷衍生物的合成、结构及络合研究
Syntheses, Structures, and Complexation Studies of Tris(organostannyl)methane Derivatives.
作者信息
Wendji Anicet Siakam, Lutter Michael, Stratmann Lukas M, Jurkschat Klaus
机构信息
Lehrstuhl für Anorganische Chemie II Fakultät für Chemie und Chemische Biologie Technische Universität Dortmund 44221 Dortmund Germany.
出版信息
ChemistryOpen. 2016 Oct 25;5(6):554-565. doi: 10.1002/open.201600092. eCollection 2016 Dec.
The syntheses of tris(organostannyl)methanes HC(SnX Ph) (, =0; , =1, X=I; , =1, X =F; , =1, X=Cl; , =1, X=OAc; , =2, X=I; , =2, X=Cl) and the organostannate complexes EtN[HC(SnIPh)⋅F] (), PhP[HC(SnClPh)⋅Cl] (), and [PhP][HC(SnClPh)⋅2 Cl] () are reported. The compounds were characterized by H, C, F, and Sn NMR spectroscopy, IR spectroscopy, electrospray mass spectrometry, and (with the exception of ) single-crystal X-ray diffraction analysis. From the reaction between and AgClO resulted the unprecedented hexanuclear organotin oxocluster [HC{Sn(ClO)Ph}Sn(OH)Ph] (), the molecular structure of which was elucidated by using X-ray crystallography.
报道了三（有机锡基）甲烷HC（SnX₃Ph）₃（n = 0；n = 1，X = I；n = 1，X = F；n = 1，X = Cl；n = 1，X = OAc；n = 2，X = I；n = 2，X = Cl）以及有机锡酸盐配合物Et₃N[HC（SnI₃Ph）·F]（）、Ph₃P[HC（SnCl₃Ph）·Cl]（）和[Ph₃P][HC（SnCl₃Ph）·2Cl]（）的合成。通过¹H、¹³C、¹⁹F和¹¹⁹Sn核磁共振光谱、红外光谱、电喷雾质谱以及（除了之外）单晶X射线衍射分析对这些化合物进行了表征。由与AgClO₄反应得到了前所未有的六核有机锡氧簇[HC{Sn（ClO₄）Ph}₂Sn（OH）Ph]₂（），其分子结构通过X射线晶体学得以阐明。
Zotero 插件