镍（II）氮杂卟啉（NCPs）与偶氮自由基引发剂的氧化反应以及通过所提出的镍（III）NCP中间体发生的意外分子内亲核取代反应。
The oxidation of Ni(II) N-confused porphyrins (NCPs) with azo radical initiators and an unexpected intramolecular nucleophilic substitution reaction via a proposed Ni(III) NCP intermediate.
作者信息
Jiang Hua-Wei, Chen Qing-Yun, Xiao Ji-Chang, Gu Yu-Cheng
机构信息
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. China.
出版信息
Chem Commun (Camb). 2009 Jul 7(25):3732-4. doi: 10.1039/b904615a. Epub 2009 May 15.
DOI:10.1039/b904615a
PMID:19557264
Abstract
The oxidation of Ni(II) N-confused porphyrins (NCPs) with azo radical initiators resulted in an unexpected intramolecular nucleophilic substitution reaction via a proposed Ni(III) NCP intermediate, which could be detected by HRMS.
摘要
镍（II）氮杂卟啉（NCPs）与偶氮自由基引发剂的氧化反应通过一个推测的镍（III）NCP中间体引发了意外的分子内亲核取代反应，该中间体可通过高分辨质谱检测到。
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