Ma Shengqian, Simmons Jason M, Yuan Daqiang, Li Jian-Rong, Weng Wei, Liu Di-Jia, Zhou Hong-Cai
Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, IL 60439, USA.
Chem Commun (Camb). 2009 Jul 21(27):4049-51. doi: 10.1039/b906605e. Epub 2009 Jun 9.
A nanotubular metal-organic framework, PCN-19, was constructed based on a micro3-oxo-trinickel basic carboxylate secondary building unit (SBU) and the 9,10-anthracenedicarboxylate ligand; its permanent porosity was confirmed by N2 adsorption isotherms, and its H2 storage performances were evaluated under both low and high pressures at 77 K.
基于一种μ3-氧代-三镍碱性羧酸盐二级结构单元（SBU）和9,10-蒽二羧酸配体构建了一种纳米管状金属有机框架PCN-19；通过N2吸附等温线证实了其永久孔隙率，并在77 K下的低压和高压条件下评估了其储氢性能。
