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基于三镍二级构筑单元的金属有机框架呈现出气吸附滞后现象。

Metal-organic framework based on a trinickel secondary building unit exhibiting gas-sorption hysteresis.

作者信息

Ma Shengqian, Wang Xi-Sen, Manis Erika S, Collier Christopher D, Zhou Hong-Cai

机构信息

Department of Chemistry & Biochemistry, Miami University, Oxford, Ohio 45056, USA.

出版信息

Inorg Chem. 2007 Apr 30;46(9):3432-4. doi: 10.1021/ic070338v. Epub 2007 Apr 4.

DOI:10.1021/ic070338v
PMID:17407286
Abstract

An interpenetrating microporous metal-organic framework based on a mu3-oxotrinickel basic carboxylate secondary building unit has been synthesized and structurally characterized. It exhibits pronounced gas-sorption hysteresis and selective adsorption of carbon dioxide over methane.

摘要

一种基于μ3-氧代三镍碱性羧酸盐二级构筑单元的互穿微孔金属有机框架已被合成并进行了结构表征。它表现出明显的气体吸附滞后现象以及对二氧化碳相对于甲烷的选择性吸附。

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