Hilt Gerhard, Danz Michael, Treutwein Jonas
Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse, 35043 Marburg, Germany.
Org Lett. 2009 Aug 6;11(15):3322-5. doi: 10.1021/ol901064p.
The application of aryl-substituted starting materials such as styrene and 1-aryl-substituted 1,3-butadiene derivatives in the cobalt-catalyzed 1,4-hydrovinylation reaction has been investigated. The use of unsymmetrical alpha,omega-dienes in the hydrovinylation with 1-aryl-1,3-butadiene led chemoselectively to the 1:1 or the 1:2 adducts depending on the stoichiometry of the starting materials.
研究了芳基取代的起始原料如苯乙烯和1-芳基取代的1,3-丁二烯衍生物在钴催化的1,4-氢乙烯基化反应中的应用。在与1-芳基-1,3-丁二烯的氢乙烯基化反应中使用不对称的α,ω-二烯，根据起始原料的化学计量比，化学选择性地生成1:1或1:2加合物。
