杂芳基溴化物中溴-镁交换反应的动力学
Kinetics of bromine-magnesium exchange reactions in heteroaryl bromides.
作者信息
Shi Lei, Chu Yuanyuan, Knochel Paul, Mayr Herbert
机构信息
Department Chemie und Biochemie der Ludwig-Maximilians-Universität Munchen, Butenandtstrasse 5-13 (Haus F), 81377 München, Germany.
出版信息
Org Lett. 2009 Aug 6;11(15):3502-5. doi: 10.1021/ol9013393.
PMID:19601592
Abstract
Competition experiments are reported which compare the relative reactivities of bromoheteroarenes toward i-PrMgCl x LiCl in THF at 0 degrees C.
摘要
报道了竞争实验，该实验比较了溴代杂芳烃在0℃下于四氢呋喃中对异丙基氯化镁·氯化锂的相对反应活性。
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