Cote Laura J, Cruz-Silva Rodolfo, Huang Jiaxing
Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208, USA.
J Am Chem Soc. 2009 Aug 12;131(31):11027-32. doi: 10.1021/ja902348k.
Graphite oxide (GO) is a promising precursor for the bulk production of graphene-based materials due to its relatively low cost of synthesis. The superior solvent processability of GO makes it particularly attractive for making composites by premixing with other materials. Typically, the reduction of GO has relied on either chemical agents or high temperature treatment. Here we report a room temperature, chemical-free flash reduction process where a photographic camera flash instantaneously triggers the deoxygenation reaction of GO by photothermal heating. Flash irradiation also rapidly creates a fused polymer composite from a random mixture of GO and polymer particles. Using a photomask, conducting patterns such as interdigitated electrode arrays can be readily made on flexible substrates.
氧化石墨烯(GO)因其相对较低的合成成本,是大规模生产石墨烯基材料的一种很有前景的前驱体。GO优异的溶剂可加工性使其在与其他材料预混合以制备复合材料方面特别具有吸引力。通常,GO的还原依赖于化学试剂或高温处理。在此,我们报道了一种室温、无化学试剂的快速还原过程,其中相机闪光灯通过光热加热瞬间触发GO的脱氧反应。闪光照射还能迅速由GO和聚合物颗粒的随机混合物形成一种熔融聚合物复合材料。使用光掩模,可以在柔性基板上轻松制作诸如叉指电极阵列等导电图案。