通过酰氧基磷鎓中间体与苄基三乙基四硫钼酸盐作为硫转移试剂合成羧酸硫酯。
Synthesis of thioesters from carboxylic acids via acyloxyphosphonium intermediates with benzyltriethylammonium tetrathiomolybdate as the sulfur transfer reagent.
机构信息
Department of Organic Chemistry, Indian Institute of Science, Bangalore 560012, India.
出版信息
J Org Chem. 2009 Aug 21;74(16):6291-4. doi: 10.1021/jo9009694.
PMID:19618897
Abstract
An efficient protocol is reported for the synthesis of thioesters from carboxylic acids with use of acyloxy phosphonium salts as intermediates and benzyltriethylammonium tetrathiomolybdate as the sulfur transfer reagent.
摘要
本文报道了一种从羧酸合成硫酯的有效方法，该方法使用酰氧基磷盐作为中间体，并用苄基三乙基四硫钼酸盐作为硫转移试剂。
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